Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.
نویسندگان
چکیده
A series of monoligated L·Pd(II)(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd(II)-mediated insertion of an aryl group into an unactivated arene.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 134 48 شماره
صفحات -
تاریخ انتشار 2012